swelling characterization of nanocomposite hydrogels of poly (acrylamide-n-vinylimidazole)
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Swelling Characterization of Nanocomposite Hydrogels of Poly (acrylamide-N-vinylimidazole)
In this study, a hydrogel composed of acrylamide (AAm) with N-vinylimidazole (NVI) as co-monomer, with a cross-linker such as N, N` Methylenebisacrylamide and potassium peroxodisulfate as an initiator solution was prepared. Poly (AAm/NVI) hydrogels were synthesized by free radical solution polymerization. Swelling experiments were performed in water at 25°C, gravimetrically. Here, it was of...
full textTemperature sensitive poly(N-t-butylacrylamide-co-acrylamide) hydrogels: synthesis and swelling behavior
A series of temperature sensitive hydrogels was prepared by free-radical crosslinking copolymerization of N-t-butylacrylamide (TBA) and acrylamide in methanol. N,N0-methylenebis(acrylamide) was used as the crosslinker. It was shown that the swelling behavior of the hydrogels can be controlled by changing the amount of TBA units in the network chains. Hydrogels immersed in dimethylsulfoxide (DMS...
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Current studies investigating properties of nanoparticle-reinforced polymers have shown that nanocomposites often exhibit improved properties compared to neat polymers. However, over two decades of research, using both experimental studies and modeling analyses, has not fully elucidated the mechanistic underpinnings behind these enhancements. Moreover, few studies have focused on developing an ...
full textEffect of compression on fast swelling of poly(acrylamide-co-acrylic acid) superporous hydrogels.
Superporous hydrogels (SPHs) swell to a large size in a very short time. In many applications it is preferred to compress SPHs to reduce the overall dimension in the dried state. The effects of compression on the swelling property of SPHs were examined. The swelling property of the compressed SPHs was dependent on the orientation of the SPHs during compression. If SPHs were compressed in an ori...
full textStructural Parameters and Swelling Behavior of pH Sensitive Poly(acrylamide-co-acrylic acid) Hydrogels
In the present work, hydrogels based on acrylamide (AAm) and acrylic acid (AAc), crosslinked with N,N’-methylenebisacrylamide (MBAAm) were prepared by free radical polymerization in solution. The effect of initial AAm/AAc mole ratio and nominal crosslinking ratio (moles of crosslinking agent/moles of polymer repeat unit) on the dynamic and equilibrium swelling behaviour of hydrogels was investi...
full textSynthesis, characterization and swelling behaviour of poly(acrylamide-co- methacrylic acid) grafted Gum ghatti based superabsorbent hydrogels
A mixture of acrylamide (AAm) and methacrylic acid (MAA) was crosslinked onto Gum ghatti (Gg) using N, N’-methylene-bis-acrylamide (MBA) as a crosslinker and ascorbic acid (ABC) and potassium persulphate (KPS) redox pair as an initiator. Optimized reaction parameters for the graft copolymerization of Gum ghatti with AAm were time (min)=90; temperature (C)=50; pH=7.0; deionized water (ml)=10; mo...
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Journal title:
quarterly journal of applied chemical researchPublisher: islamic azad university, karaj branch
ISSN 2008-3815
volume 9
issue 2 2015
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